Brunner, Henri, Gehart, G., Meier, Walter, Wachter, Joachim, Riedel, Astrid, Elkrami, S., Mugnier, Y. and Nuber, B. (1994) Preparative, structural, and electrochemical investigations on peralkylated niobocene dichlorides and difluorides. Organometallics 13 (1), pp. 134-140.
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Abstract
CP(dagger)2NbCl2 (CP(dagger) = 175-C5Me4Et) (1b) was synthesized from NbCl5 and a slight excess of Cp(dagger)Li and NaBH4. Its electrochemical (2 e-, E1/2 = -1.6 V) and chemical reduction (2 equiv of Na/Hg) was studied showing that peralkylation of the Cp ligand facilitates two-electron reduction compared to less substituted CP2NbHal2 derivatives. The reduced solutions of CP*2NbCl2 (CP* = C5Me5) ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1994 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 23017 |
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