Schwarz, Patrick, Wachter, Joachim and Zabel, Manfred (2011) Suppression of Realgar Cage Degradation during Complexation: Formation of Hybrid Coordination Polymers with As4S4, PAs3S3, and Cu(I) Halide Building Blocks. Inorganic chemistry : Inorg. Chem. 50, pp. 12692-12696.
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Abstract
Realgar, As4S4, reacts with Cr(CO)5THF under cage degradation to give As4S3·Cr(CO)5 (1). The reverse structural change is found if solutions of 1 in CH2Cl2 react with equimolar amounts of PAs3S3·W(CO)5 and CuX (X = Cl, Br, I) in CH3CN under biphasic diffusion conditions. The resulting coordination polymers 2–4 contain a reconstituted realgar molecule along with the PAs3S3 cage. The crystal ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2011 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 23022 |
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