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Einfluß verschiedenartig substituierter Cyclopentadienylliganden auf die Chemie schwefelreicher Organometallkomplexe mit Metallen der 6. Nebengruppe ( = INFLUENCE OF DIFFERENTLY SUBSTITUTED CYCLOPENTADIENYL LIGANDS ON CHEMISTRY OF ORGANOMETAL COMPLEXES WITH SULFUR)

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Brunner, Henri ; Grassl, Roland ; Meier, Walter ; Wachter, Joachim ; Nuber, Bernd ; Ziegler, M. L.
Date of publication of this fulltext: 05 Jan 2012 08:46


The reaction of the differently substituted cyclopentadienyl complexes L2M2(CO)4 with sulfur is investigated with respect to the ligand L (etmcp = ethyltetramethylcyclopentadienyl, tbcp = t-butylcyclopentadienyl, ipcp = isopropylcyclopentadienyl) and the metal M (Cr, Mo, W). For M = Cr the only isolated product is etmcp2Cr2S5. For M = Mo three isomers A, D, E of composition L2Mo2S4 (L = ipcp, ...


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