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The Reaction of [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters

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Brunner, Henri ; Gehart, G. ; Nuber, B. ; Wachter, Joachim ; Ziegler, M. L.
Date of publication of this fulltext: 04 Jan 2012 15:23


An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the ``underside'' is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. Cp+ = eta-5-EtMe4C5.

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