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The Reaction of [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters
Brunner, Henri, Gehart, G., Nuber, B., Wachter, Joachim and Ziegler, M. L. (1992) The Reaction of [CP2+NB2(B2H6)2] (CP+ = ETA-ETME4C5) with Sulfur: Stabilization of the Tetrathioborato Ligand in Novel Sulfido Niobium Clusters. Angewandte Chemie, International Edition in English 31 (8), pp. 1021-1023.Date of publication of this fulltext: 04 Jan 2012 15:23
Article
DOI to cite this document: 10.5283/epub.23042
Abstract
An equilateral Nb3 triangle the edges of which are spanned by a BS4 tetrahedron and bridged by sulfido ligands on the ``underside'' is found in cluster 1. The synthesis of this cluster with an unusual electron configuration shows that tetrathioborates can serve as ligands in organometallic chemistry. Cp+ = eta-5-EtMe4C5.
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| Item type | Article | ||||
| Journal or Publication Title | Angewandte Chemie, International Edition in English | ||||
| Publisher: | Wiley-VCH | ||||
|---|---|---|---|---|---|
| Volume: | 31 | ||||
| Number of Issue or Book Chapter: | 8 | ||||
| Page Range: | pp. 1021-1023 | ||||
| Date | 1992 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Unknown | ||||
| Created at the University of Regensburg | Unknown | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-230424 | ||||
| Item ID | 23042 |
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