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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-230457
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.23045
Zusammenfassung
The reaction of Cp2*Mo2S4I2(Cp* = eta(5)-C5Me5) with two equivalents of NaSR (R = Me, (i)Pr, (t)Bu, Ph) gives the complexes Cp2*Mo2(mu,eta(1)-SSR)2(mu-S)2 (2a-d) in nearly quantitative yields. The compounds have been investigated spectroscopically and in the case of R = Ph (2d) by means of X-ray diffraction analysis. The results show the presence of two eta(1)-PhSS- bridges (d(s-s) 2.139(2) ...
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