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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-230469
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.23046
Zusammenfassung
The previously described reaction of Cp'2NbH3 (Cp' = t-BuC5H4) with S8 was investigated with regard to the kinetic stabilization of as yet elusive intermediates during the formation of the polysulfide complex Cp'4Nb2S9 (1). Therefore, the permethylated complex Cp*2NbS3H (2; Cp* = C5Me5) and the Ta complex Cp'2TaS2H (3) were synthesized in a related reaction and structurally investigated. Despite ...
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