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New Discoveries in the Realm of Metal–Metal Multiple Bonds:[η5-(C5Me5)Co2], the First Organometallic Multiple-Bond Complex without Bridging Ligands

Wachter, Joachim (1991) New Discoveries in the Realm of Metal–Metal Multiple Bonds:[η5-(C5Me5)Co2], the First Organometallic Multiple-Bond Complex without Bridging Ligands. Angewandte Chemie, International Edition in English 30 (9), pp. 1120-1121.

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Abstract

Double bond, yes or no? That is the poignant question in the case of the complex [Cp*CoCoCp*] prepared by J.J. Schneider et al. The Co-Co distance and the number of electrons suggest a double bond, while the H-1-NMR spectrum and the poor reactivity toward C2H4 and CO would suggest the contrary. Nevertheless, with this unbridged complex, the prerequisite for the synthesis of further such compounds and for studying the properties of these multibond systems was realized.


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Item type:Article
Date:1991
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1002/anie.199111201DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:23048
Owner only: item control page

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