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Visible light mediated homo- and heterocoupling of benzyl alcohols and benzyl amines on polycrystalline cadmium sulfide

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Mitkina, Tatiana ; Stanglmair, Christoph ; Setzer, Wolfgang ; Gruber, Michael ; Kisch, Horst ; König, Burkhard
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 11 Apr 2012 05:19


The oxidative coupling of sp3 hybridized carbon atoms by photocatalysis is a valuable synthetic method as stoichiometric oxidation reagents can be avoided and dihydrogen is the only byproduct of the reaction. Cadmium sulfide, a readily available semiconductor, was used as a visible light heterogeneous photocatalyst for the oxidative coupling of benzyl alcohols and benzyl amines by irradiation ...


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