Visible light mediated homo- and heterocoupling of benzyl alcohols and benzyl amines on polycrystalline cadmium sulfide

URN to cite this document:: urn:nbn:de:bvb:355-epub-237491
DOI to cite this document:: 10.5283/epub.23749

Mitkina, Tatiana ; Stanglmair, Christoph ; Setzer, Wolfgang ; Gruber, Michael ; Kisch, Horst ; König, Burkhard

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Date of publication of this fulltext: 11 Apr 2012 05:19

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Abstract

The oxidative coupling of sp3 hybridized carbon atoms by photocatalysis is a valuable synthetic method as stoichiometric oxidation reagents can be avoided and dihydrogen is the only byproduct of the reaction. Cadmium sulfide, a readily available semiconductor, was used as a visible light heterogeneous photocatalyst for the oxidative coupling of benzyl alcohols and benzyl amines by irradiation ...