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Dynamics and spatial correlations of tetrapentylammonium ions in acetonitrile

Kunz, Werner ; Turq, P. ; Bellisent-Funel, M.-C. ; Calmettes, P.

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Abstract

Quasielastic neutron scattering (QENS) spectra were measured for a 0.43 M solution of n‐tetrapentylammonium bromide in deuterated acetonitrile at 25 °C, 5 °C, and −15 °C. Values of the translational diffusion coefficient of the cations were inferred from these data using a simple model of translation and rotation. These values are significantly higher than the ones obtained by nuclear magnetic ...

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