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Thermotropic Phase Behavior of Choline Soaps

Klein, Regina ; Dutton, Helen ; Diat, Oliver ; Tiddy, Gordon J. T. ; Kunz, Werner



Abstract

Choline carboxylates (ChCm with m = 12-18) are simple biocompatible anionic surfactants with very low Krafft temperatures, possessing a rich aqueous phase behavior. In the present work, we have investigated the thermotropic mesomorphism of anhydrous ChCm salts for m = 12-18. Transition temperatures and enthalpies determined by differential scanning calorimetry reveal that all investigated ...

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