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Hydration of Formate and Acetate Ions by Dielectric Relaxation Spectroscopy

Rahman, H.M.A. ; Hefter, Glenn ; Buchner, Richard



Abstract

Dielec. relaxation (DR) spectra have been measured for aq. solns. of sodium formate (NaOFm) and sodium acetate (NaOAc) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89) up to solute concns. c .ltorsim. 3.2 M and .ltorsim. 3.7 M, resp., at 25°. Measurements were also made on NaOAc(aq) at 15 ≤ T/°C ≤ 35. In addn. to the usual dominant bulk-water relaxation process at ∼20 GHz, one or two further ...

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