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Dielectric spectroscopy of ion-pairing and hydration in aqueous tetra-n-alkylammonium halide solutions

Buchner, Richard ; Hoelzl, C. ; Stauber, J. ; Barthel, Josef



Abstract

Complex permittivity spectra of aq. solns. of Me4NBr, Et4NCl, Et4NBr, Pr4NBr, Bu4NBr, and Pe4NBr were detd. in the frequency range 0.2 ≤ ν/GHz ≤ 89. At 25°, data cover electrolyte concns. up to the satn. limit. Addnl., selected concns. of Pr4NBr and Bu4NBr were investigated as a function of temp. The spectra of Me4NBr, Et4NCl, and Et4NBr exhibit three dispersion steps which can be assigned - ...

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