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Correlation between polarity parameters and dielectric properties of [Na][TOTO] - a sodium ionic liquid

Zech, Oliver ; Hunger, J. ; Sangoro, Joshua ; Iacob, Ciprian ; Kremer, Friedrich ; Kunz, Werner ; Buchner, Richard



Abstract

The ionic liq. (IL) [Na][TOTO], with sodium as the cation and an oligoethercarboxylate as the anion, shows properties that differ significantly from conventional ionic liqs., like imidazolium salts. Its polarity, detd. in the temp. range of (293-333) K from measurements of Reichardt's ENT value and the Kamlet-Taft parameters is extraordinarily low and matches the dielec. const. extrapolated from ...

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