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Description of dilution enthalpies and heat capacities for aqueous solutions within the MSA-NRTL model with ion solvation

Simonin, Jean-Pierre, Bernard, Olivier, Papaiconomou, Nicolas and Kunz, Werner (2008) Description of dilution enthalpies and heat capacities for aqueous solutions within the MSA-NRTL model with ion solvation. Fluid Phase Equilibria 264 (1-2), pp. 211-219.

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Abstract

The capability of the MSA-NRTL model to describe heat effects for binary aq. electrolyte and nonelectrolyte solns., with a relatively reduced no. of parameters, is examd. The thermodn. properties described include the osmotic coeff., .vphi., the apparent relative molar enthalpy, ΦL, and the apparent molar heat capacity, ΦCP. The MSA-NRTL model consists of the mean spherical approxn. (MSA) for ...

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Item type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1016/j.fluid.2007.11.018DOI
Keywords:electrolyte nonelectrolyte aq soln thermodn simulation MSA NRTL model
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24504
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