Abstract
The capability of the MSA-NRTL model to describe heat effects for binary aq. electrolyte and nonelectrolyte solns., with a relatively reduced no. of parameters, is examd. The thermodn. properties described include the osmotic coeff., .vphi., the apparent relative molar enthalpy, ΦL, and the apparent molar heat capacity, ΦCP. The MSA-NRTL model consists of the mean spherical approxn. (MSA) for ...
Abstract
The capability of the MSA-NRTL model to describe heat effects for binary aq. electrolyte and nonelectrolyte solns., with a relatively reduced no. of parameters, is examd. The thermodn. properties described include the osmotic coeff., .vphi., the apparent relative molar enthalpy, ΦL, and the apparent molar heat capacity, ΦCP. The MSA-NRTL model consists of the mean spherical approxn. (MSA) for the long-range electrostatic contribution to the Gibbs energy (for ionic solns.) and a local compn. model, the non-random two-liq. (NRTL) model for the short-range contribution.
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