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Description of dilution enthalpies and heat capacities for aqueous solutions within the MSA-NRTL model with ion solvation

Simonin, Jean-Pierre ; Bernard, Olivier ; Papaiconomou, Nicolas ; Kunz, Werner



Abstract

The capability of the MSA-NRTL model to describe heat effects for binary aq. electrolyte and nonelectrolyte solns., with a relatively reduced no. of parameters, is examd. The thermodn. properties described include the osmotic coeff., .vphi., the apparent relative molar enthalpy, ΦL, and the apparent molar heat capacity, ΦCP. The MSA-NRTL model consists of the mean spherical approxn. (MSA) for ...

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