Simonin, Jean-Pierre, Bernard, Olivier, Papaiconomou, Nicolas and Kunz, Werner (2008) Description of dilution enthalpies and heat capacities for aqueous solutions within the MSA-NRTL model with ion solvation. Fluid Phase Equilibria 264 (1-2), pp. 211-219.
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Abstract
The capability of the MSA-NRTL model to describe heat effects for binary aq. electrolyte and nonelectrolyte solns., with a relatively reduced no. of parameters, is examd. The thermodn. properties described include the osmotic coeff., .vphi., the apparent relative molar enthalpy, ΦL, and the apparent molar heat capacity, ΦCP. The MSA-NRTL model consists of the mean spherical approxn. (MSA) for ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2008 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz | ||||
| Identification Number: |
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| Keywords: | electrolyte nonelectrolyte aq soln thermodn simulation MSA NRTL model | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 24504 |
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