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Inclusion of Ionic Hydration and Association in the MSA-NRTL Model for a Description of the Thermodynamic Properties of Aqueous Ionic Solutions: Application to Solutions of Associating Acids

Simonin, Jean-Pierre, Krebs, Stéphane and Kunz, Werner (2006) Inclusion of Ionic Hydration and Association in the MSA-NRTL Model for a Description of the Thermodynamic Properties of Aqueous Ionic Solutions: Application to Solutions of Associating Acids. Industrial & Engineering Chemistry Research 45 (12), pp. 4345-4354.

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Abstract

Ionic hydration and assocn. are included in the MSA-NRTL model for a description of the thermodn. properties of aq. ionic solns. Hydration effects are introduced using the classic model of Robinson and Stokes, in which hydration nos. are independent of salt concn. Assocn. is accounted for through a mass action law. New compact conversion formulas are given expressing the individual ionic, and ...

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Item type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/ie051312jDOI
Keywords:acid aq soln ion hydration assocn thermodn model
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24538
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