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Vapor pressures, osmotic and activity coefficients of electrolytes in protic solvents at different temperatures. Part 1. Lithium bromide in methanol

Nasirzadeh, Karamat ; Papaiconomou, Nicolas ; Neueder, Roland ; Kunz, Werner



Abstract

Precise vapor pressure data for LiBr solns. in MeOH are given for temps. ranging from 298.15-333.15 K. The molality range is from 0.0411-6.8675 mol-kg-1. Osmotic coeffs. were calcd. by taking into account the 2nd virial coeff. of MeOH. The parameters of the Pitzer-Mayorga model, the Archer extension of the Pitzer-Mayorga model, the mole-fraction-based thermodn. model of Clegg-Pitzer, and the ...

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