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Description of Vapor-Liquid Equilibria for CO2 in Electrolyte Solutions Using the Mean Spherical Approximation

Papaiconomou, Nicolas, Simonin, Jean-Pierre, Bernard, Olivier and Kunz, Werner (2003) Description of Vapor-Liquid Equilibria for CO2 in Electrolyte Solutions Using the Mean Spherical Approximation. Journal of Physical Chemistry B 107 (24), pp. 5948-5957.

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Abstract

The mean spherical approxn. is used to describe the vapor pressure over aq. solns. contg. an electrolyte and carbon dioxide. Three electrolytes have been studied: NaOH, NaCl, and acetic acid. A good representation was obtained with a reduced no. of parameters as compared to previous models. These parameters account for the concn. and temp. dependence of the solute sizes and the relative ...

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Item type:Article
Date:2003
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/jp034294xDOI
Keywords:electrolyte carbon dioxide aq soln VLE mean spherical approxn
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24611
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