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Description of Vapor-Liquid Equilibria for CO2 in Electrolyte Solutions Using the Mean Spherical Approximation

Papaiconomou, Nicolas ; Simonin, Jean-Pierre ; Bernard, Olivier ; Kunz, Werner



Abstract

The mean spherical approxn. is used to describe the vapor pressure over aq. solns. contg. an electrolyte and carbon dioxide. Three electrolytes have been studied: NaOH, NaCl, and acetic acid. A good representation was obtained with a reduced no. of parameters as compared to previous models. These parameters account for the concn. and temp. dependence of the solute sizes and the relative ...

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