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Synthesis and Electrochemical Properties of Some Lithium Chelatophosphates

Eberwein, Michael ; Schmid, A. ; Schmidt, M. ; Zabel, M. ; Burgemeister, T. ; Barthel, Josef ; Kunz, Werner ; Gores, H.-J.


Two new Li chelatophosphates were synthesized, purified, and characterized, Li tris[3,4,5,6-tetrafluor-1,2-benzenediolato(2-)-O,O']-phosphate(1-) and Li tris[3-fluoro-1,2-benzenediolato(2-)-O,O']-phosphate(1-). A precursor, the corresponding acid of Li tris[3,4,5,6-tetrafluor-1,2-benzenediolato(2-)-O,O']-phosphate(1-), H+[P(C6F4O2)3]-, presumably a super acid, shows a hexacoordinated phosphorous ...


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