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Selective complexation of copper ions in monolayers of a new amphiphilic cage molecule at the liquid/air and liquid/liquid interfaces

Galet, L. ; Pezron, I. ; Kunz, Werner ; Larpent, C. ; Zhu, J. ; Lheveder, C.


The authors report studies of a newly synthesized cyclam deriv. with 4 chain substituents (tetra-(N-2-tetradecyl-carboxamidoethyl)-tetraazacyclotetradecane; TC14) which could be of interest for the selective liq.-liq. extn. of cations. The authors studied the monolayer properties of TC14 mols. spread at the aq. soln./air interface by surface pressure-area isotherm measurements and Brewster angle ...


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