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Small hydrophobic organic ions in aqueous solutions

Kunz, Werner, Calmettes, P., Cartailler, T. and Turq, P. (1993) Small hydrophobic organic ions in aqueous solutions. Journal of Chemical Physics 99 (3), pp. 2074-2078.

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Small-angle neutron scattering expts. were performed at 25° on solns. of tetraphenylphosphonium chloride and sodium tetraphenylborate in deuterated water and in deuterated DMF. The results show a strong attraction between either the org. cations or the org. anions when the salts are dissolved in water. In the org. solvent the attraction between the equally charged org. ions is very weak. This is the 1st structural evidence of hydrophobic assocn. of small org. ions in water.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
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Keywords:hydrophobic org ion aq soln tetraphenylphosphonium chloride water DMF soln sodium tetraphenylborate water DMF soln
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24643
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