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Osmotic coefficients of nonaqueous electrolyte solutions at thermodynamic and McMillan-Mayer level

Barthel, Josef ; Neueder, Roland ; Kunz, Werner



Abstract

Precise osmotic coeffs. from abs. vapor pressure measurements on various electrolyte solns. of org. solvents are given as the ref. data for use in relative vapor pressure measurement methods. The availability of reliable data is used for a study of the interdependence of thermodn. properties and theor. and exptl. McMillan-Mayer level methods, such as chem. model and hypernetted chain calcns. and small angle neutron scattering expts.


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