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Conductance in electrolyte solutions using the mean spherical approximation

Bernard, Olivier, Kunz, Werner, Turq, P. and Blum, L. (1992) Conductance in electrolyte solutions using the mean spherical approximation. Journal of Physical Chemistry 96 (9), pp. 3833-3840.

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The elec. conductance of ionic solns. is studied within the context of Fuoss-Onsager theory using equil. pair correlation functions from the hypernetted chain equation and the mean spherical approxn. Simple anal. expressions are obtained using the mean spherical approxn. for the equil. pair correlation function. The agreement with exptl. data of NaCl, KBr, BaCl2, and LaCl3 is found to be very good, considering that there are no adjustable parameters.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
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Keywords:cond elec ionic soln Fuoss Onsager theory ionic cond mean spherical approxn cond equil pair correlation function cond chloride soln cond theory expt
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24659
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