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Dielectric Relaxation of Dilute Aqueous NaOH, NaAl(OH)4, and NaB(OH)4

Buchner, Richard ; Hefter, Glenn ; May, P. M. ; Sipos, P.


The complex dielec. permittivity of aq. NaOH (c ≤ 2M) and of dil. (≤0.6M) NaAl(OH)4 and NaB(OH)4 solns. in NaOH ([Na] = 1M) at 25° has been detd. in the frequency range 0.2 ≤ ν/GHz ≤ 20. All spectra could be represented by a single Cole-Cole relaxation time distribution attributed to the cooperative relaxation of the solvent. The concn. dependence of the effective hydration no. of OH- has been ...


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