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Ion-pair and solvent relaxation processes in aq. Na2SO4 solutions

Buchner, Richard ; Capewell, S. G. ; Hefter, Glenn ; May, P. M.


The complex dielec. permittivity of aq. sodium sulfate solns. (0.025 ≤ c/mol dm-3 ≤ 1.6) was detd. in the frequency range 0.2 ≤ ν/GHz ≤ 20 with a com. dielec. measurement system based on a vector network analyzer. The dielec. permittivity spectra were supplemented with interpolated literature data at 12 ≤ ν/GHz ≤ 89. To fit the spectra, a superposition of three Debye relaxation processes was ...


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