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Kinetic processes in the liquid phase studied by high-frequency permittivity measurements

Buchner, Richard ; Barthel, Josef


A review with 59 refs.; the application of dielec. relaxation studies to the kinetic processes of ion-pair formation, cooperative mol. processes and H-bonding dynamics in the liq. phase is discussed. For electrolyte solns. an equation is derived which links the exptl. relaxation time of the solute, τIP, with the rate consts. of ion-pair formation and decompn.; results are presented and the ...


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