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Dielectric relaxation of electrolyte solutions in acetonitrile

Barthel, Josef, Kleebauer, M. and Buchner, Richard (1995) Dielectric relaxation of electrolyte solutions in acetonitrile. Journal of Solution Chemistry 24 (1), pp. 1-17.

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Complex permittivity spectra in the frequency range 0.95 ≤ ν (GHz) ≤ 89 for acetonitrile and its solns. of LiBr, NaI, NaClO4, and Bu4NBr at 25°C show one Debye equation for the neat solvent whereas the superposition of a Debye process for the solute and a Cole-Cole distribution for the solvent is necessary to account for the dielec. relaxation behavior of the solns. The reorientation of bulk ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:complex permittivity electrolyte soln acetonitrile
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24875
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