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Dielectric relaxation of electrolyte solutions in acetonitrile

Barthel, Josef ; Kleebauer, M. ; Buchner, Richard



Abstract

Complex permittivity spectra in the frequency range 0.95 ≤ ν (GHz) ≤ 89 for acetonitrile and its solns. of LiBr, NaI, NaClO4, and Bu4NBr at 25°C show one Debye equation for the neat solvent whereas the superposition of a Debye process for the solute and a Cole-Cole distribution for the solvent is necessary to account for the dielec. relaxation behavior of the solns. The reorientation of bulk ...

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