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Dielectric relaxation of aqueous electrolyte solutions. II. Ion-pair relaxation of 1:2, 2:1, and 2:2 electrolytes

Barthel, Josef ; Hetzenauer, H. ; Buchner, Richard


The low-frequency relaxation process contributing to the complex permittivity spectra of aq. solns. of MgSO4, CdSO4, Na2SO4, CdCl2, and CuCl2 is investigated. The dispersion amplitudes are analyzed with the help of model calcns., based on a modified Cavell equation for ellipsoidal bodies. Ion pairs are responsible for the low-frequency relaxation process with solvent sepd. ion pairs dominating ...


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