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Far-infrared studies of molecular dynamics and interactions in N,N-dimethylformamide

Buchner, Richard ; Yarwood, J.


Far-IR diln. measurements on DMF in carbon tetrachloride provide data on which to base an assessment of the way in which both the short-ranged and long-ranged dynamics are dependent on the surrounding mol. interactions. While there is an obvious increase in the rate of the long-time reorientational motion on diln., the short-time dynamics appear to be relatively weakly affected. This is ...


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