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Protecting Nanoscaled Non-oxidic Particles from Oxygen Uptake by Coating with Nitrogen-Containing Surfactants

Müller, Rainer ; Knapp, Michael ; Heckmann, Klaus ; Von Ruthendorf, M. ; Boden, G.


To suppress the reactivity of nanoscaled nonoxidic powders of Ti nitride (TiN) and Si carbonitride (SiCN) against hydrolysis and oxidn., chem. surface modification with N-contg. surfactants was studied. Among these surfactants, long-chain primary amines, ethylenediamines, guanidines, nitriles, isocyanates, and succinimides were examd. TG, elemental anal., and behavior against the H2O-vapor ...


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