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Cyclopentadiene Annelated [2.2]Paracylophanes: Novel Ligands Toward Multilayered Metal Complexes

Buchholz, Herwig, Reiser, Oliver and Meijere, Armin de (1991) Cyclopentadiene Annelated [2.2]Paracylophanes: Novel Ligands Toward Multilayered Metal Complexes. Synlett 1991 (1), pp. 20-22.

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Other URL: http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-1991-20612


Pauson-Khand reactions of [2.2]paracyclophane-1,9-diene (2) and [2.2]paracyclophan-1-ene (3) with various acetylenes and octacarbonyldicobalt lead to monocyclopentenone anellated derivatives 5/6 and biscyclopentenone anellated derivative synanti-7 which can be converted to cyclopentadiene anellated systems 10/11 and 13. Their deprotonation with methyllithium yields cyclopentadienyl anions, ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:258
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