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Stabilization of Proline Enamine Carboxylates by Amine Bases

Schmid, Markus Benedikt ; Zeitler, Kirsten ; Gschwind, Ruth Maria


As part of our ongoing studies to provide an experimental basis for the improved understanding of organocatalytic reaction mechanisms we present a study on the influence of amine bases on enamine intermediate stabilization in proline catalysis. The (partial) deprotonation of the proline acid function is displayed by characteristic shifts of certain proton resonances and is also manifested by an ...


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