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Coherent and Incoherent Interactions between Cofacial Pi-Conjugated Oligomer Dimers in Macrocycle Templates

Liu, Sue ; Schmitz, Daniela ; Jester, Stefan-S. ; Borys, Nicholas J. ; Höger, Sigurd ; Lupton, John M.



Abstract

The interactions between two π-conjugated oligomers templated in molecular scaffolds are revealed as a function of separation and orientation, providing models of intermolecular interactions in bulk organic semiconductor materials. For a variety of dimer geometries (acyclic and macrocyclic) of the same model oligomer, no change in fluorescence spectra, fluorescence dynamics, or low-temperature ...

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