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Palladium Catalyzed Coupling Reactions of 2,3-Dihydrofuran Using High Pressure Conditions

Hillers, Stephan ; Reiser, Oliver



Abstract

High presure dramatically influences the palladium catalyzed reaction of 2,3-dihydrofuran (1) and aryl compounds (2-X). An increased activity of the catalyst even in the absence of phosphine ligands has been observed. Nevertheless, using a large excess of ligands does not inhibit the catalyst, however, the regioselectivity of the products strongly depends on the amount of ligand employed. Last ...

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