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Fast separations by capillary electrophoresis hyphenated to electrospray ionization time-of-flight mass spectrometry as a tool for arsenic speciation analysis

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Niegel, Claudia ; Pfeiffer, Simon A. ; Grundmann, Marco ; Arroyo-Abad, Uriel ; Mattusch, Jürgen ; Matysik, Frank-Michael
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 05 Dec 2012 11:18


Fast capillary electrophoresis (CE) hyphenated to time-of-flight mass spectrometry (TOF-MS) of four organoarsenic species (glycerol oxoarsenosugar, sulfate oxoarsenosugar, arsenobetaine, arsenocholine) are presented using short length CE capillaries under high electric field strengths of up to 1.3 kV cm−1 with small inner diameter (ID). The separation of arsenosugars by CE is demonstrated for the ...


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