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Acyloxybutadiene tricarbonyl iron complexes as enzyme-triggered CO-releasing molecules (ET-CORMs): a structure-activity relationship study

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Romanski, Steffen ; Kraus, Birgit ; Guttentag, Miguel ; Schlundt, Waldemar ; Rücker, Hannelore ; Adler, Andreas ; Neudörfl, Jörg-Martin ; Alberto, Roger ; Amslinger, Sabine ; Schmalz, Hans-Günther
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 17 Dec 2012 06:30


A series of η4-acyloxycyclohexadiene–Fe(CO)3 complexes was prepared and fully characterized by spectroscopic methods including single crystal X-ray diffraction. For this purpose a new synthetic access to differently acylated 1,3- and 1,5-dienol–Fe(CO)3 complexes was developed. The enzymatically triggered CO release from these compounds was monitored (detection of CO through GC and/or by means of ...


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