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Novel pathways for the coordination and activation of the E4 tetrahedron (E4 = P4, AsP3, As4)

Schwarzmaier, Christoph (2014) Novel pathways for the coordination and activation of the E4 tetrahedron (E4 = P4, AsP3, As4). PhD, Universität Regensburg.

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Date of publication of this fulltext: 16 Jan 2014 16:55

Abstract (English)

The thesis deals with the activation and coordination of the reactive molecular modifications of phosphorus and arsenic. By carefully chosen reaction conditions, it is possible to selectively break one or more bonds of the native tetrahedral molecules to yield novel structural motifs. Moreover, the highly unstable yellow arsenic can be stabilized in the coordination sphere of transition metal ...

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Translation of the abstract (German)

Die Arbeit beschäftigt sich mit der Aktivierung and Koordination der reaktiven, molekularen Elementmodifikationen des Phosphors und Arsens. Durch spezielle Reaktionsbedingungen ist es möglich, eine oder mehrere Bindungen der nativen, tetraedrischen Moleküle selektiv zu spalten und so neuartige Strukturmotive zu erhalten. Darüber hinaus kann das hochreaktive gelbe Arsen in der Koordinationsspäre ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:16 January 2014
Referee:Prof. Dr. Manfred Scheer
Date of exam:30 November 2012
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:phosphorus, arsenic, coordination chemistry, small molecule activation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:27176
Owner only: item control page

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