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Zum Reaktionsverhalten verbrückender Pentelidenkomplexe

Stubenhofer, Markus (2013) Zum Reaktionsverhalten verbrückender Pentelidenkomplexe. PhD, Universität Regensburg.

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Date of publication of this fulltext: 02 Dec 2013 15:17

Abstract (German)

In Rahmen der Dissertation wurde das Reaktionsverhalten verbrückter Pentelidenkomplexe Cp*E[W(CO)5]2 (E = P, As) untersucht. Der erste Teil behandelt das Redoxverhalten und die Eigenschaften der radikalischen Verbindungen [(CO)5W(P2E(sMes)2)W(CO)4] (E = P, As), welche durch Photolyse der Pentelidenkomplexe in Gegenwart von (sMes)P=P(sMes) dargestellt wurden. Der zweite Teil der Arbeit befasst ...

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Translation of the abstract (English)

In this dissertation the reactivity of bridged pentelidene complexes Cp*E[W(CO)5]2 (E = P, As) was investigated. The first part of the work describes the redox-behavior and properties of the radicals [(CO)5W(P2E(sMes)2)W(CO)4] (E = P, As), which were synthesized by photolysis of the pentelidene complexes in the presence of (sMes)P=P(sMes). The second part deals with the reactions of different ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:2 December 2013
Referee:Prof. Dr. Manfred Scheer and Prof. Dr. Henri Brunner
Date of exam:21 December 2012
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Phosphor, Phosphiniden, Arsen, Arsiniden, Pentelidenkomplexe, Lewis-Säure, Lewis-Base, Addukte, Photolyse, Radikale, phosphorus, arsenic, phosphinidene, arsinidene
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:27202
Owner only: item control page

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