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Visible-Light-Mediated α-Arylation of Enol Acetates Using Aryl
Diazonium Salts

Hering, Thea, Hari, Durga Prasad and König, Burkhard (2012) Visible-Light-Mediated α-Arylation of Enol Acetates Using Aryl
Diazonium Salts.
The Journal of Organic Chemistry 77 (22), pp. 10347-10352.

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Abstract

Visible light mediates efficiently the α-arylation of enol acetates by aryl diazonium salts under mild conditions using [Ru(bpy)(3)]Cl(2) as a photoredox catalyst. The broad scope of the reaction toward various diazonium salts and enol acetates was explored. The application of this reaction in the concise synthesis of 2-substituted indoles was demonstrated.


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Item type:Article
Date:2012
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/jo301984pDOI
23101908PubMed ID
Keywords:visible light photoredox catalysis, α-arylation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:27409
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