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Hydrophilic and Hydrophobic Hydration of Sodium Propanoate and Sodium Butanoate in Aqueous Solution

Rahman, H.M.A. ; Hefter, Glenn ; Buchner, Richard



Abstract

Aq. solns. of sodium propanoate (NaOPr) and n-butanoate (NaOBu) have been studied at concns. of c ⪅ 3 M by broadband dielec. relaxation spectroscopy over the frequency range 0.2 ≤ ν/GHz ≤ 89 at 25 °C. Three relaxation modes were resolved, centered at (approx.) 1, 8, and 18 GHz, for both sets of solns. The two faster modes were assigned to the cooperative relaxation of "slow" and bulk water ...

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