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Organic chemistry under hydrothermal conditions

Avola, Sabine ; Guillot, Marie ; Da Silva-Perez, Denilson ; Pellet-Rostaing, Stephane ; Kunz, Werner ; Goettmann, Frederic


At elevated temp., several properties of water are strongly altered compared to what our daily experience tells us: the dielec. const. of water, for example, is reduced, so that water can more easily solubilize org. mols. In addn., the self-dissocn. const. of water is increased (by three orders of magnitude at 250 °C), thus favoring H+- and OH--catalyzed reactions. Surprisingly, while ...


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