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Organic chemistry under hydrothermal conditions

Avola, Sabine, Guillot, Marie, Da Silva-Perez, Denilson, Pellet-Rostaing, Stephane, Kunz, Werner and Goettmann, Frederic (2013) Organic chemistry under hydrothermal conditions. Pure and Applied Chemistry 85 (1), pp. 89-103.

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At elevated temp., several properties of water are strongly altered compared to what our daily experience tells us: the dielec. const. of water, for example, is reduced, so that water can more easily solubilize org. mols. In addn., the self-dissocn. const. of water is increased (by three orders of magnitude at 250 °C), thus favoring H+- and OH--catalyzed reactions. Surprisingly, while ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
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Keywords:green chemistry; organic chemistry; solvents; water
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:28165
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