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The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

Hari, Durga Prasad ; König, Burkhard



Abstract

The use of diazonium salts for aryl radical generation and CH arylation processes has been known since 1896 when Pschorr first used the reaction for intramolecular cyclizations. Meerwein developed it further in the early 1900s into a general arylation method. However, this reaction could not compete with the transition-metal-mediated formation of C(sp2)C(sp2) bonds. The replacement of the copper ...

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