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Formation and Characterization of a Molecule–Metal–Molecule Bridge in Real Space

Albrecht, Florian ; Neu, Mathias ; Quest, Christina ; Swart, Ingmar ; Repp, Jascha


Metal–organic complexes were formed by means of inelastic excitations in a scanning tunneling microscope (STM). The electronic structure of the complex was characterized using STM imaging and spectroscopy. By exploiting the symmetry of the complex, its electronic structure can be rationalized from linear combinations of molecular orbitals. The actual bonding geometry, which cannot be inferred ...


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