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Dielectric Relaxation Spectroscopy Shows a Sparingly Hydrated Interface and Low Counterion Mobility in Triflate Micelles

Lima, P.S. ; Chaimovich, H. ; Cuccovia, I.M. ; Buchner, Richard



Abstract

The properties of ionic micelles are affected by the nature of the counterion. Specific ion effects can be dramatic, inducing even shape and phase changes in micellar solns., transitions apparently related to micellar hydration and counterion binding at the micellar interface. Thus, detg. the hydration and dynamics of ions in micellar systems capable of undergoing such transitions is a crucial ...

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