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Apparent molal volumes of symmetrical and asymmetrical isomers of tetrabutylammonium bromide in water at several temperatures

Moreno, Nicolas ; Malagon, Andres ; Buchner, Richard ; Vargas, Edgar F.



Abstract

Apparent molal vols. of a series of differently substituted quaternary ammonium bromides, namely tetra-​iso-​butyl-​, tetra-​sec-​butyl-​, tetra-​n-​butyl-​, di-​n-​butyl-​di-​sec-​butyl- and di-​n-​butyl-​di-​iso-​butylammonium bromide have been detd. as a function of molal concn. at (298.15, 303.15 and 308.15) K. Partial molar volumes at infinite diln. and ionic molar volumes of these ...

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