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Bottom-Up Self-Assembly of Amorphous Core-Shell-Shell Nanoparticles and Biomimetic Crystal Forms in Inorganic Silica-Carbonate Systems.

Eiblmeier, Josef ; Kellermeier, Matthias ; Deng, Mao ; Kienle, Lorenz ; Kunz, Werner ;



Abstract

Mineralization of alkaline-earth carbonates in silica rich media at high pH leads to fascinating crystal morphologies that strongly resemble products from biomineralization, despite the absence of any organic matter. Recent work has demonstrated that elaborate CaCO3 structures can be grown in such systems even at high supersaturation, as nanoparticles of amorphous calcium carbonate (ACC) were ...

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