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The effect of silica on polymorphic precipitation of calcium carbonate: an on-line energy-dispersive X-ray diffraction (EDXRD) study

Kellermeier, Matthias ; Glaab, Fabian ; Klein, Regina ; Melero-Garcia, Emilio ; Kunz, Werner ; Garcia-Ruiz, Juan Manuel


Calcium carbonate is the most abundant biomineral and a compd. of great industrial importance. Its pptn. from soln. has been studied extensively and was often shown to proceed via distinct intermediate phases, which undergo sequential transformations before eventually yielding the stable cryst. polymorph, calcite. In the present work, we have investigated the crystn. of calcium carbonate in a ...


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