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Octanol-rich and water-rich domains in dynamic equilibrium in the pre-ouzo region of ternary systems containing a hydrotrope

Diat, Oliver ; Klossek, Michael ; Touraud, Didier ; Deme, Bruno ; Grillo, Isabelle ; Kunz, Werner ; Zemb, Thomas


Ternary mixts. of medium-chain fatty alcs., water and a hydrotrope (such as ethanol), near the immiscibility gap, make stable single phases at const. temp. Interestingly, in this `pre-ouzo region' these single phases consist of two distinct nanoscopic pseudo-phases, one octanol-rich and one water-rich. This domain of compn., which is known to produce strong light scattering and to sep. under ...


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