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Cleavable carbamate linkers for controlled protein delivery from hydrogels

Hammer, Nadine ; Brandl, Ferdinand ; Kirchhof, Susanne ; Goepferich, Achim


The reversible attachment of proteins to polymers is one potential strategy to control protein release from hydrogels. In this study, we report the reversible attachment of lysozyme to poly(ethylene glycol) (PEG) by degradable carbamate linkers. Phenyl groups with different substituents were used to control the rate of carbamate hydrolysis and the resulting protein release. Sodium dodecyl sulfate ...


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