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Asymmetric Aminohydroxylation of Heteroaromatic Acrylates

Raatz, Dirk, Innertsberger, Clara and Reiser, Oliver (1999) Asymmetric Aminohydroxylation of Heteroaromatic Acrylates. Synlett 1999 (12), pp. 1907-1910.

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Other URL: http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-1999-2973


N-, S- and O-heteroaromatic acrylates were aminohydroxylated with generally high regio- and enantioselectivity. While pyridylacrylates are not amenable towards this process, the corresponding N-oxides proved to be a useful substitute, allowing the access to biologically important pyridine substituted taxolTM side chain analogs.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Keywords:aminohydroxylations; amino acids; asymmetric catalysis; taxolTM (paclitaxel); pyridines
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:306
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