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Asymmetric Aminohydroxylation of Heteroaromatic Acrylates

Raatz, Dirk ; Innertsberger, Clara ; Reiser, Oliver


N-, S- and O-heteroaromatic acrylates were aminohydroxylated with generally high regio- and enantioselectivity. While pyridylacrylates are not amenable towards this process, the corresponding N-oxides proved to be a useful substitute, allowing the access to biologically important pyridine substituted taxolTM side chain analogs.

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