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Reduction of aryl halides by consecutive visible light-induced electron transfer processes

Ghosh, Indrajit, Ghosh, Tamal, Bardagi, Javier I. and König, Burkhard (2014) Reduction of aryl halides by consecutive visible light-induced electron transfer processes. Science 346, pp. 725-728.

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Abstract

Biological photosynthesis uses the energy of several visible light photons for the challenging oxidation of water, whereas chemical photocatalysis typically involves only single-photon excitation. Perylene bisimide is reduced by visible light photoinduced electron transfer (PET) to its stable and colored radical anion. We report here that subsequent excitation of the radical anion accumulates ...

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Item type:Article
Date:2014
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1055/s-0034-1380350DOI
25378618PubMed ID
10.1126/science.1258232DOI
Keywords:photoredox catalysis - reduction - aryl halides - visible light
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:30964
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