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Reduction of aryl halides by consecutive visible light-induced electron transfer processes

Ghosh, Indrajit ; Ghosh, Tamal ; Bardagi, Javier I. ; König, Burkhard



Abstract

Biological photosynthesis uses the energy of several visible light photons for the challenging oxidation of water, whereas chemical photocatalysis typically involves only single-photon excitation. Perylene bisimide is reduced by visible light photoinduced electron transfer (PET) to its stable and colored radical anion. We report here that subsequent excitation of the radical anion accumulates ...

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